硬合物和软粗粒度大分子混合物的相位行为
Umashankar Erigi1, Umesh Dhumal1, Mukta Tripathy1
1Indian Institute of Technology Bombay, Powai, Mumbai, Maharashtra 400076, India.
The Journal of chemical physics
|October 23, 2023
概括
硬合物和软宏分子的混合物表现出令人惊的微相分离. 这种由有效的吸引力驱动的现象,导致独特的共存有序和无序结构.
科学领域:
- 软物质物理学 软物质物理学
- 体科学是一门关于体的科学.
- 聚合物物理 聚合物物理
背景情况:
- 软的宏分子,如聚合物和树突分子,通常表现出纯粹的排斥性相互作用.
- 了解涉及硬和软成分的混合物的相位行为对于材料科学至关重要.
研究的目的:
- 为了研究由硬合物和软粗粒度大分子组成的混合物的结构和相位行为.
- 阐明这种混合系统中自组装和相分离背后的机制.
主要方法:
- 使用的参考交互站点模型 (RRISM) 理论.
- 采用分子动力学 (MD) 模拟来分析系统行为.
主要成果:
- 鉴定了由于耗尽效应导致的硬合体和软宏分子之间的中介诱导的有效吸引力.
- 在低和高硬合物分量时观察到宏相分离.
- 在中间组合中发现了微相分离到富含硬质和富含软质的域,形成了无序的双连续形态.
- 描述了硬富域为有序的FCC结构,软富域为无序的集群流体.
结论:
- 这项研究揭示了纯排斥性,同otropic colloids 的系统中的新型微相分离,归因于接口软化.
- 由此产生的共存的有序 (FCC) 和无序 (集群流体) 域呈现出一种独特的,同时有序和无序的状态.
- 这些发现为设计具有可调节性质的复杂软物质架构提供了洞察力.
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