在波罗的海的硫化沉积物中的调动
Chunyang Zhou1, Yue Gao2, Hao Zhang3
1Center for Water Research, Advanced Institute of Natural Sciences, Beijing Normal University at Zhuhai, Zhuhai 519087, China; Analytical, Environmental and Geo-Chemistry (AMGC), Vrije Universiteit Brussel (VUB), Pleinlaan 2, 1050 Brussels, Belgium.
The Science of the total environment
|October 23, 2023
概括
从硫化沉积物中释放的 (P) 与铁 (Fe), (Mn) 和硫 (S) 有关. 动员机制因深度而异,受不稳定的P池和氧化铁/Mn碳酸盐溶解的影响.
科学领域:
- 地质化学 地质化学
- 环境科学 环境科学
- 海洋化学 海洋化学
背景情况:
- 沉积物中的 (P) 行为与铁 (Fe) 和 (Mn) 有关,但在长期的硫化环境中不清楚.
- 波罗的海的哥特兰盆地为研究这些关系提供了一个关键的硫化沉积物环境.
研究的目的:
- 研究硫化沉积物中的P调动与Fe,Mn和S的关系.
- 澄清不同沉积物深度的P来源和释放机制.
- 了解性P池在沉积物补给中的作用.
主要方法:
- 沉积物切片和固体相序列提取.
- 在现场的薄膜 (DGT) 扩散梯度采样.
- 在沉积物中DGT诱导的流量 (DIFS) 建模和视觉MINTEQ计算.
主要成果:
- 确定了两个P来源:P含铁氧化物/Mn碳酸盐 (浅处) 的溶解和来自不同来源 (最深处) 的释放.
- 证实了与Mn/Fe同时释放P,尽管由于Fe硫化物形成而溶解Fe的含量较低.
- 沉积物性池的大小决定了P的补给能力,正如DIFS建模所显示的那样.
结论:
- 实验和理论方法成功阐明了硫化沉积物中的P,Fe,Mn和S关系.
- 这些发现有助于更好地了解硫化水域中的P循环.
- 在硫化沉积物环境中,深度依赖的P动员机制至关重要.
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