在凝结后,有助于高残留可溶的有机物质的组成和结构识别
Yitian He1, Xin Huang2, John van Leeuwen3
1Key Laboratory of Drinking Water Science and Technology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; University of Chinese Academy of Sciences, Beijing 100049, China.
The Science of the total environment
|October 24, 2023
概括
(Al) 与溶解有机物 (DOM) 的复合影响饮用水处理. 和酸化合物,特别是那些含有硫酸组的化合物,对可溶性Al-DOM复合物有显著的贡献,有助于剩余Al的控制.
科学领域:
- 环境化学环境化学
- 水处理科学水处理科学
背景情况:
- 控制饮用水中的剩余 (Al) 是至关重要的.
- 与溶解有机物 (DOM) 的复合会影响治疗的有效性.
研究的目的:
- 确定涉及可溶性有机结合Al形成的DOM组成和结构.
- 在接近中性pH的凝血过程中了解Al-DOM复合机制.
主要方法:
- 高分辨率和精确的质谱仪.
- 在pH值7.50.0的凝固实验.
- 对DOM结构和功能组的分析.
主要成果:
- 溶性有机结合Al主要涉及和酸化合物.
- 具有硫酸组的化合物增强了Al水解和单体/寡体Al-DOM复合体的形成.
- 这些具有1-4个碳基的DOM分子 (m/z < 350) 占可溶性Al.的80%以上.
结论:
- 特定的DOM结构,特别是硫化,驱动可溶性Al-DOM复合.
- 了解这些DOM特征是优化凝血和残留Al去除的关键.
- 将凝固与有针对性的有机去除过程相结合,可以改善饮用水质量.
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