通过化学聚合和化学化抑制离子迁移到稳定的矿太阳能电池
Jiakang Zhang1, Xueqing Niu1, Cheng Peng1
1College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, 266042, Qingdao, P. R. China.
Angewandte Chemie (International ed. in English)
|October 25, 2023
概括
将Apronal聚合物纳入矿膜可以通过减少缺陷和离子迁移,将太阳能电池效率提高到25.09%. 这一策略提高了商业矿太阳能电池应用的稳定性和性能.
科学领域:
- 材料科学 材料科学 材料科学
- 可再生能源可再生能源是可再生能源.
- 固态化学 固态化学
背景情况:
- 矿太阳能电池中的离子迁移导致不稳定,限制了商业化.
- 不协调的Pb2+和酸盐空缺等缺陷阻碍了设备的性能.
研究的目的:
- 为了提高矿太阳能电池的效率和长期稳定性.
- 为了减轻离子迁移和缺陷的有害影响.
主要方法:
- 将N-carbamoyl-2-propan-2-ylpent-4-enamide (Apronal) 单体纳入矿膜中.
- 在矿层内形成一个交联聚合物 (P-Apronal) 的热交联.
- 电影质量的表征,能量水平对齐和设备性能.
主要成果:
- 通过与浅层缺陷相互作用,P-Apronal形成改善了膜结晶性,并减少了网格应变.
- 改进的能量水平调整和电荷载体提取导致了25.09%的冠军效率.
- P-Apronal有效地抑制了化离子迁移,显著改善了设备的稳定性.
结论:
- 在高效率的矿太阳能电池中,采用Apronal是一种可行的策略.
- 交叉连接的P-Apronal提高了材料质量和设备的操作稳定性.
- 这种方法解决了矿太阳能电池商业化的主要挑战.
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