硫酸盐活性煤气化的孔孔特征 煤渣水泥糊回填矿用矿用矿物
Geng Xie1,2, Yonglu Suo1,3, Lang Liu4,5,6
1Energy School, Xi'an University of Science and Technology, Xi'an, 710054, China.
Environmental science and pollution research international
|October 25, 2023
概括
将3%的硫酸添加到改性煤气化渣-水泥凝糊补充剂 (MCGS-CPB) 中,可以优化机械性能和孔隙结构. 由于膨胀应力和裂,较高度会降低性能.
科学领域:
- 材料科学 材料科学 材料科学
- 地质技术工程 地质技术工程
- 废物管理 废物管理
背景情况:
- 煤炭固体废物,如煤炭气化废渣,面临着处置的挑战.
- 回收煤炭气化废渣作为煤矿填充材料提供了一个可持续的解决方案.
- 改性煤炭气化渣-水泥糊填充 (MCGS-CPB) 是煤矿填充的一个有前途的材料.
研究的目的:
- 调查硫酸对MCGS-CPB的机械性能和孔隙结构的影响.
- 为了确定用于煤矿填充的MCGS-CPB的最佳硫酸含量.
- 了解MCGS-CPB在不同硫酸度下演变的过程.
主要方法:
- 制备的MCGS-CPB与不同硫酸盐含量 (1-5%).
- 测试单轴压力强度 (UCS),以评估机械性能.
- 侵入孔径测量 (MIP) 和微观测试,以分析孔隙结构特征.
主要成果:
- 硫酸显著影响MCGS-CPB的UCS和孔隙结构.
- 在3%的硫酸兴奋剂下观察到最佳性能;在这个水平以上发生恶化.
- 中和微尺度分析揭示了孔隙结构的变化和过度硫酸的膨胀应力形成.
结论:
- 3%的硫酸含量优化了MCGS-CPB的机械性能和孔隙结构.
- 过度的硫酸 (>3%) 会导致膨胀应力,微裂和缩小宏观机械性能.
- 硫酸刺激的MCGS-CPB用于煤矿填充的最佳应用比率不应超过3%.
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