吸附到生物炭修改土壤的动力学
1Food Animal Environmental System Research Unit, US Department of Agriculture - Agricultural Research Service, Bowling Green, KY, 42104, United States.
Chemosphere
|October 25, 2023
概括
将铁涂层生物炭 (BCFe) 添加到土壤中,显著改变了 (P) 吸附动力学,影响因土壤类型而异. 没有修改的生物炭 (BC) 对P吸附动态的影响很小.
科学领域:
- 土壤科学 土壤科学
- 环境化学环境化学
- 生物地质化学生物地质化学
背景情况:
- 生物炭是一种潜在的土壤修改剂,可以增强 (P) 吸收.
- 对生物炭的氧化铁 (Fe) 涂层可以增加P吸收,但其在土壤中的动力效应尚不清楚.
研究的目的:
- 在四种具有对比性质的土壤中研究P吸附的动力学,这些土壤中修改了未经修改的生物炭 (BC) 和涂有Fe的生物炭 (BCFe).
- 确定BC和BCFe对P吸附量和随时间推移的动态行为的影响.
主要方法:
- 四种具有不同质地和表面特性的土壤被修改为5% (w/w) BC或BCFe.
- 酸吸附测量在化时间从1到314小时.
- 用五种动力模型来评估生物炭修改的影响,调配了吸数据.
主要成果:
- 没有修改的生物炭 (BC) 在所有土壤中对P吸收的影响很小.
- 涂有Fe的生物炭 (BCFe) 在低P吸收土壤中显著增加了P吸收,但在高P吸收土壤中显示出低于预期的增加.
- 动力模型参数在所有四种土壤中都受到BCFe的显著改变,在两个土壤中受到BC的显著改变.
结论:
- 涂有Fe的生物炭显示了增强P吸收的潜力,但其有效性取决于土壤.
- 添加BCFe显著改变了修改土壤中P吸附的动力学.
- 这项研究为了解生物炭-土壤-P相互作用提供了关键的动力学数据.
相关概念视频
The Phosphorus Cycle
37.2K
Unlike carbon, water, and nitrogen, phosphorus is not present in the atmosphere as a gas. Instead, most phosphorus in the ecosystem exists as compounds, such as phosphate ions (PO43-), found in soil, water, sediment and rocks. Phosphorus is often a limiting nutrient (i.e., in short supply). Consequently, phosphorus is added to most agricultural fertilizers, which can cause environmental problems related to runoff in aquatic ecosystems.
37.2K
Factors Affecting Solubility
33.5K
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:
33.5K


