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Updated: Jul 12, 2025

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes

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过渡金属催化CC键的形成来自CC激活

Feijie Song1, Biqin Wang1, Zhang-Jie Shi2

  • 1College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, Sichuan 610066, P. R. China.

Accounts of chemical research
|October 26, 2023
PubMed
概括

这项研究展示了过渡金属催化C-C键激活策略,使复杂分子从简单的酒精,碳酸盐和合成成为可能. 这些方法提供了高效的碳骨架重新排列,并在有机合成中改善了原子经济.

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Properties of Organometallic Compounds

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Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists...
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