新型NASICON型Na-V-Mn-Ni含有高速率和长寿命SIBs的阴极
Ruoyu Chen1, Xinyu Zhang2,3, Dongdong Li1
1College of Physics, the State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, International Center of Future Science, Jilin University, Changchun, 130012, China.
Small (Weinheim an der Bergstrasse, Germany)
|October 26, 2023
概括
在离子电池 (SIB) 中用和部分替代可以提高阴极性能. 一种新的NASICON型复合材料VMN-0.5证明了高级SIB应用的优越电化学性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 固态化学 固态化学
背景情况:
- 离子电池 (SIB) 是一个有前途的储能解决方案.
- 优化阴极材料对于SIB性能至关重要.
- 在Na3V2(PO4)3 (NVP) 中部分替代过渡金属可以增强电化学性能.
研究的目的:
- 为了合成和描述新型NASICON类型的酸盐复合材料.
- 研究Mn/Ni替代V对电化学性能的影响.
- 为了阐明优化复合材料中的储存机制.
主要方法:
- 复合材料制造的索尔凝方法.
- 基于同步射线的X射线研究,XRD和XPS用于结构和化学分析.
- 电化学技术包括循环电压测量和静电间歇定位.
主要成果:
- 成功合成了纳西康类型的Na-V-Mn-Ni酸盐复合物.
- 在晶体结构中成功地用Mn/Ni替代V.
- 确定了Na3.83V1.17Mn0.58Ni0.25(PO4)3 (VMN-0.5) 作为具有高容量的最佳组成 (108.1mAhg-1在0.2°C).
- 在准固态金属电池中,VMN-0.5表现出色.
结论:
- /替代有效地增强了基于NVP的NASICON材料的电化学特性.
- VMN-0.5显示出作为SIBs的高性能阴极的巨大潜力.
- 这些发现支持NASICON型材料用于离子电池的商业化.
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