坚固且可回收的相隔超分子凝通过脱水-水化循环
Xiaohui Xu1, Yannick L Eatmon2, Kofi S S Christie3,4
1Department of Chemical and Biological Engineering, Princeton University, Princeton, New Jersey 08540, United States.
JACS Au
|October 27, 2023
概括
研究人员开发了一种新方法,只使用水,从弱的水凝中制造出坚固,可回收的水凝. 这些相隔凝 (PSG) 为软机器人和传感器等应用提供了增强的稳定性和环境耐受性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 软物质物理学 软物质物理学
背景情况:
- 水凝对软机器人和自主传感有希望.
- 挑战包括机械稳定性和可持续的加工/处置.
- 现有的水凝往往缺乏耐用性和环境弹性.
研究的目的:
- 开发一种可持续的方法来制造机械坚固和可回收的水凝.
- 克服当前水凝材料在稳定性和环境影响方面的局限性.
- 设计具有增强性和环境耐受性的水凝.
主要方法:
- 为了处理水凝,采用了脱水-水化方法.
- 这种方法诱导了相位分离和超分子域的形成.
- 在整个过程中,用水作为唯一的溶剂.
主要成果:
- 将软弱的水凝转化为坚硬的,可回收的超分子相隔凝 (PSG).
- 由于相隔领域的物理交叉链接,PSG表现出增强的性和伸展性.
- PSGs在广泛的pH范围 (1-14) 中表现出环境耐受性,以及对过度膨胀/收缩的抗性.
- 成功地将PSG作为应变传感器在空气和水环境中使用.
结论:
- 脱水-水化方法为高性能水凝提供了一条可持续的途径.
- 分相超分子凝 (PSG) 为要求高的应用提供了传统水凝的可行替代方案.
- PSG显示出在先进传感器和软机器人系统中使用的巨大潜力.
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