从地下水中去除铁和氨的新型移植凝:一种合成和计算化学研究
H M Abd El-Salam1, Ali M El Shafey1, Abdelouahid Samadi2
1Polymer Research Laboratory, Department of Chemistry, Faculty of Science, Beni-Suef University, Beni-Suef City 62514, Egypt.
Gels (Basel, Switzerland)
|October 27, 2023
概括
一种新的水凝有效地从地下水中去除铁和氨. 这种吸附剂显示出高效率,可以再生,为净化水提供可持续的解决方案.
科学领域:
- 环境化学环境化学
- 聚合物科学 聚合物科学
- 水处理 处理水的方法
背景情况:
- 地下水被铁和氨污染是一个重大的环境问题.
- 开发高效和可再生的吸附剂对于净水至关重要.
研究的目的:
- 为了合成和评估一个多烯酸-多烯酸化物水凝与3-chloroaniline移植用于铁和氨去除.
- 为了研究水凝的吸附机制和效率.
- 使用密度函数理论 (DFT) 探索水凝复合的理论方面.
主要方法:
- 用于水凝合成的添加聚合技术.
- 批量吸附实验用于研究时间,剂量和温度的影响.
- 异热运动吸附模型.
- 密度函数理论 (DFT) 计算 (B3LYP/6-311G(d,p 和 LANL2DZ) 用于理论分析.
主要成果:
- 合成的水凝证明有效地去除了铁 (98.3%) 和氨 (100%).
- 吸附效率对动时间,剂量和温度都很敏感.
- DFT计算证实了水凝对所研究的酸盐的选择性,并提供了对复杂化机制的见解.
结论:
- 接种的水凝是一种高效和可再生的吸附剂,用于从地下水中去除铁和氨.
- 该研究提供了水凝性能的实验和理论验证.
- 这种材料为可持续的水处理提供了一个有希望的解决方案.
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