结构性和双极板相关性质的偏差电压依赖性 阴极弧沉积碳基涂层的阴极弧沉积碳基涂层
Maximilian Steinhorst1,2, Maurizio Giorgio1, Teja Roch1
1Project Group at the Dortmunder OberflächenCentrum DOC, Fraunhofer Institute for Material and Beam Technology IWS, Eberhardstr. 12, 44145 Dortmund, Germany.
ACS applied materials & interfaces
|October 27, 2023
概括
这项研究优化了金属双极板不钢上的碳基涂层. 600V偏向电压产生了最佳的耐腐蚀性和出色的导电性,使其成为燃料电池应用的理想选择.
科学领域:
- 材料科学 材料科学 材料科学
- 表面工程是什么?表面工程是什么?
- 电化学 电化学 电化学
背景情况:
- 金属双极板对于燃料电池至关重要.
- 开发耐用和导电性涂层对于它们的性能至关重要.
- 碳基涂料为这种应用提供了有前途的性能.
研究的目的:
- 为了研究偏向电压对碳基涂层的影响.
- 为了优化结构,电气和电化学性能.
- 为金属双极板确定合适的涂层.
主要方法:
- 阴极弧蒸发用于涂层沉积.
- 在碳沉积过程中变化的偏向电压 (1-900 V).
- 使用拉曼光谱,TEM,EELS和潜在动力极化试验进行表征.
主要成果:
- 偏差电压显著影响涂层结构,从石墨到无形.
- 观察到优良的电导率,与较低的接口接触电阻 (1.5-4 mΩ cm2).
- 在600V偏差电压下沉积的涂层表现出优越的耐腐蚀性.
结论:
- 偏向电压是定制碳涂层特性的一个关键参数.
- 600V的碳涂样品显示了导电性和耐腐蚀性之间的良好平衡.
- 这种优化的涂层非常适合用于燃料电池中的金属双极板应用.
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