基于纤维素的聚乙烯碳酸盐作为高兼容性,有效性和耐迁移的塑化剂,用于聚 (乳酸)
Jihuai Tan1, Min Yu1, Tongtong Zhang2
1College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, People's Republic of China.
International journal of biological macromolecules
|October 27, 2023
概括
高度兼容的纤维素衍生物,基于纤维素的聚乙烯碳酸盐 (CPPEC),显著增强了聚乳酸 (PLA) 的特性. 这一创新改进了PLA的性能.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 生物材料工程 生物材料工程
背景情况:
- 纤维素增强了多乳酸 (PLA) 的强度,但界面兼容性差限制了应用.
- 开发兼容的纤维素衍生物对于先进的PLA复合材料至关重要.
研究的目的:
- 为了合成高度兼容的基于纤维素的聚乙烯碳酸盐 (CPPEC),用于增强PLA.
- 调查CPPEC对PLA机械,低温和迁移抵抗性能的影响.
主要方法:
- 纤维素通过化和随后的以酸,黄油酸和油酸的化进行了修饰.
- 合成的CPPEC与PLA混合,以创建复合材料.
- 进行了机械测试,低温耐力评估和迁移耐力测试.
主要成果:
- 基于纤维素的聚乙烯酸 (CPPEA) 显著改善了PLA在断裂时的延长 (630.9%) 和低温耐受 (146.3%).
- 与使用氧化大豆油和二氧化甲酸的PLA相比,PLA/CPPEA表现出更高的迁移抗性.
- 在CPPEC中基和甲基的协同作用提高了PLA矩阵的兼容性.
结论:
- CPPEC证明了PLA的卓越性能提升.
- 开发的CPPEC适用于PLA行业的大规模工业应用.
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