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深度欧性溶剂涂层氧化物纳米颗粒基于聚硫膜,以减轻环境毒理学

Saif-Ur-Rehman^1,2, Muhammad Shozab Mehdi³, Muhammad Fakhar-E-Alam⁴

¹Department of Chemical Engineering, COMSATS University Islamabad, Lahore Campus, Defence Road, Off Raiwind Road, Lahore 54000, Punjab, Pakistan.

Molecules (Basel, Switzerland)

|October 28, 2023

概括

这项研究开发了先进的混合矩阵膜 (MMM),使用用深度性溶剂 (DES) 修改的纳米粒子. 这些新的DES-ceria NP膜显示了更好的二氧化碳 (CO2) 分离性能,为气体混合物净化提供了有前途的解决方案.

科学领域:

材料科学材料科学材料科学
化学工程是化学工程的重要组成部分.
环境科学环境科学

背景情况:

混合矩阵膜 (MMM) 对于气体分离至关重要.
接口工程是提高MMM性能的关键.
菌纳米粒子 (NPs) 和深层菌溶剂 (DES) 提供独特的材料特性.

研究的目的:

为了合成和描述经过DES修饰的Ceria NP填充剂.
制造和评估包含DES-ceria NP填充剂的MMM.
为了研究填充剂加载对膜特性和气体分离性能的影响.

主要方法:

纤维素NP和DES的合成.
用 DES 修改 ceria NP,以创建 DES-ceria NP 填充剂.
使用溶液造与不同的填充物负载 (2-8%) 制造MMM.
使用SEM,FTIR和TGA进行表征.
气体透测试用于二氧化碳分离.

主要成果:

SEM证实了DES-ceria NP填充剂在聚硫矩阵中的均分散.
FTIR分析表明,聚合物和填充剂之间没有不良反应.
TGA证明了膜的高热稳定性,随着填充剂的加载而增加.
观察到二氧化碳透性的显著改善以及对CO2/CH4和CO2/N2的增强选择性.

结论:

基于DES-ceria NP的MMM具有出色的热稳定性和均的填充剂分散.
与原始膜相比,开发的MMM显示出更高的二氧化碳分离效率.
这些发现突显了DES-ceria NP MMMs在气体混合物中有效减轻二氧化碳的潜力.

关键词:

谢里亚纳米粒子是什么意思深层欧性溶剂深层欧性溶剂气体分离器的气体分离器接口工程接口工程接口工程膜膜膜膜膜膜膜

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