温度对中等等级煤的分子结构的影响 通过富里埃变换红外光谱法
Meng Wu1,2, Yong Qin1,2, Yunhu Qin1
1Jiangsu Mineral Resources and Geological Design and Research Institute, China National Administration of Coal Geology, Xuzhou 221006, China.
福利埃变换红外光谱学揭示了热处理中等级煤结构的变化. 温度上升降低了硫含量,改变了碳化合物和功能组组成,影响了有机物质的成熟和凝结.
科学领域:
- 有机地化学 有机地化学
- 材料科学 材料科学 材料科学
- 频谱学是一种光谱学.
背景情况:
- 中级煤在热应力下经历结构变化.
- 了解这些变化对于煤炭利用和转化过程至关重要.
- 福里埃变换红外光谱法 (FTIR) 是分子分析的一个有价值的工具.
研究的目的:
- 研究中低温热处理中等级煤的分子结构演变.
- 分析碳化合物结构,功能组和矿物质含量的变化.
- 为了将光谱参数与热处理温度相关联.
主要方法:
- 福里埃变换红外光谱法 (FTIR) 用于分析煤炭样品.
- 确定了关键的光谱参数,如CH2/CH3比率,芳香度 (f),有机物成熟度 (M) 和芳香凝结度 (Dc).
- 此外,还评估了矿物质含量的变化 (高岩,高岩,高岩,高岩,高岩).
主要成果:
- 热处理降低了硫含量,并增加了C/H比.
- 矿物成分随着温度的升高而从高岩/岩转变为多洛岩/血岩.
- 基结构显示以太氧的减少和自我关联的基团的增加;基含量增加,而芳香C=C振动最初上升然后下降.
结论:
- 热处理缩短脂肪侧链,增加分支,并最初增强然后减少有机物质的成熟度和凝结.
- 在热处理过程中,FTIR光谱参数有效地跟踪煤炭的结构变化.
- 建议进行进一步的研究,将FTIR与13C NMR,XRD和TG-MS等技术结合起来,以进行全面的煤炭结构分析.
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