基于PVA/H3PO4矩阵的2D灵活固态超级电容器的电化学比较
Bianca K Muñoz1, Andrés González-Banciella1, Daniel Ureña1
1Material Science and Engineering Area, Universidad Rey Juan Carlos, ESCET, C/Tulipán s/n. Móstoles, 28933 Madrid, Spain.
Polymers
|October 28, 2023
概括
研究人员使用改性碳纤维开发了新的灵活超级电容器. 最好的设备,利用碳气凝和织成的玻璃纤维,在曲测试中表现出色的性能和耐用性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 灵活的电子设备需要先进的储能解决方案.
- 超级电容器提供高功率密度和长周期寿命.
- 修改碳纤维材料可以提高超级电容器的性能.
研究的目的:
- 为了研究碳气凝,氧化铜纳米粒子和素修饰对柔性超级电容器编织碳纤维的影响.
- 使用各种分离器制造和评估对称柔性超级电容器 (SFSC).
- 评估制造的设备的电化学性能和机械稳定性.
主要方法:
- 使用碳气凝 (CAG),氧化铜纳米粒子 (CuO-NPs) 和素 (LIG) 制造改性织造碳纤维 (WCF) 的SFSC.
- 电化学表征包括电容,功率密度和能量密度测量.
- 机械测试包括曲测试,以评估电容保持和稳定性.
主要成果:
- 在H3PO4/PVA中使用的CAG/WGF/CAG装置表现出卓越的性能:1.4 F/g,0.961 W/kg,0.161 Wh/kg.
- 超级电容器在曲期间和曲后表现出极好的电化学稳定性,保持其电容量的96.12%.
- 一个平行连接的双超级电容器实现了高面积容量311mF/cm2.
结论:
- 制造过程,确保完整的纤维/层嵌入凝电解质,对于有效的超级电容器功能至关重要.
- 修改后的WCF材料,特别是CAG,显著提高了灵活的超级电容器性能.
- 由于其强大的电化学特性和机械灵活性,开发的SFSC显示出灵活电子应用的有前途潜力.
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