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相关概念视频

Trends in Lattice Energy: Ion Size and Charge02:54

Trends in Lattice Energy: Ion Size and Charge

23.9K
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
23.9K
Boundary Conditions for Current Density01:25

Boundary Conditions for Current Density

878
Current density becomes discontinuous across an interface of materials with different electrical conductivities. The normal component of the current density is continuous across the boundary.
878
Metal-Semiconductor Junctions01:24

Metal-Semiconductor Junctions

355
The contact of metal and semiconductor can lead to the formation of a junction with either Schottky or Ohmic behavior.
Schottky Barriers
Schottky barriers arise when a metal with a work function (Φm) contacts a semiconductor with a different work function (Φs). Initially, electrons transfer until the Fermi levels of the metal and semiconductor align at equilibrium. For instance, if Φm > Φs, the semiconductor Fermi level is higher than the metal's before contact. The...
355
Carrier Transport01:21

Carrier Transport

450
The generation of electrical current in semiconductors is fundamentally driven by two mechanisms: drift and diffusion. These processes are essential for the functionality and performance of semiconductor-based devices.
Drift Current:
The drift of charge carriers is started by an external electric field (E). Charged particles, such as electrons and holes, experience an acceleration between collisions with lattice atoms. For electrons, this results in a drift velocity (vd) given by:
450
Current Density01:21

Current Density

4.1K
The total amount of current flowing through one unit value of a cross-sectional area is referred to as current density. If the current flow is uniform, the amount of current flowing through a conductor is the same at all points along the conductor, even if the conductor area varies. The current density consists of the local magnitude and direction of the charge flow, which varies from point to point. Current density is measured in amperes per meter square, and direction is defined as the net...
4.1K
Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

26.6K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
26.6K

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相关实验视频

Updated: Jul 12, 2025

Analysis of Contact Interfaces for Single GaN Nanowire Devices
11:13

Analysis of Contact Interfaces for Single GaN Nanowire Devices

Published on: November 15, 2013

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关联/石榴石接口的微观结构和电流密度.

Cheng Ouyang1, Hongpeng Zheng1, Qiwen Chen1

  • 1State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China.

ACS applied materials & interfaces
|October 28, 2023
PubMed
概括

通过控制形态来优化固态电池电解质是防止丝生长的关键. 在石榴石电解质中减少孔隙和增加粒度边界可以提高稳定性和性能,从而更安全地储存能量.

科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 储能 储能 储能 储能 储能 储能

背景情况:

  • 固态电池提供先进的储能潜力.
  • 固体电解质中的丝形成是它们广泛采用的主要障碍.

研究的目的:

  • 为了研究石榴石类型固体电解质的形态如何影响它们对丝透的抗性.
  • 开发和验证一种用于评估电解质对丝的电解质电阻的新方法.

主要方法:

  • 使用循环线性扫描电压测量来评估对丝的电解质电阻.
  • 凯尔文探针力显微镜和有限元素方法模拟被用来分析微观结构对离子运输的影响.

主要成果:

  • 观察到固体电解质形态与抵抗丝形成之间存在强烈的相关性.
  • 电解质具有最小化的毛孔和众多的粒度边界表现出优越的性能,达到3.2 mA cm-2的临界电流密度.
  • 通过优化形态学,实现了长期增强的循环稳定性.

结论:

  • 尽量减少毛孔,并创造一个统一的形态与小粒和丰富的粒边界是抑制的透至关重要的.
  • 控制微观结构对于开发强大而安全的固态电池至关重要.
关键词:
LLZOZO LLZO 在线观看临界电流密度 临界电流密度接口 接口 接口 接口 接口电灯是的发电线.微观结构的微观结构

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