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Updated: Jul 12, 2025

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自制纹理的四亚富烯晶膜

St John Whittaker1, Merritt McDowell1, Justin Bendesky1

  • 1Department of Chemistry, Molecular Design Institute, New York University, New York, New York 10003, United States.

Chemistry of materials : a publication of the American Chemical Society
|October 30, 2023
PubMed
概括

在四亚富瓦烯 (TTF) 材料中的晶体扭曲导致自发的图案形成. 暴露于甲醇蒸汽诱导了显著的晶体重组和重组,证明了材料科学的概括性路径.

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Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
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