煤中的磁性表达揭示了对流体运输的影响
Benjamin Nicot1, Jean-Pierre Korb2, Isabelle Jolivet1
1TotalEnergies, Avenue Larribau, 64000 Pau, France.
Magnetic resonance (Gottingen, Germany)
|October 31, 2023
概括
页岩油中的流体运输受到煤化物内的磁性合的阻碍,这种现象延迟了石油的流动性. 瓦纳基和有机基质之间的这种可逆相互作用解释了这些复杂的地质材料中观察到的异常低的透性.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 石油地质学 石油地质学
背景情况:
- 页岩油具有复杂的有机和无机物质的双孔网络.
- 页岩油的极低的流体透性还没有完全被理解.
- 了解流体运输机制对于碳化合物回收和地质储存至关重要.
研究的目的:
- 阐明导致页岩油中流体运输显著减少的机制.
- 研究有机-无机相互作用在流体扩散中的作用.
- 为了确定这些源岩中的异常低透率的起源.
主要方法:
- 联合核和电子磁共振 (MR) 技术.
- 扫描电子显微镜 (SEM) 成像.
- 在封闭的有机/无机矩阵中分析流体扩散动力学.
主要成果:
- 证据表明,由于氨酸中的瓦纳基和有机基质之间的磁性合,氨酸内部存在磁性相互作用.
- 证明这种磁性合可显著减缓流体扩散.
- 观察到所识别的合机制是可逆的.
结论:
- 煤化物中的磁性合是解释页岩石中石油极低流动性的关键机制.
- 这种现象为阻碍复杂层次矩阵中流体扩散的因素提供了新的洞察力.
- 鉴定的机制可能与其他具有封闭流体和嵌入有机/无机基的系统有关.
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