具有可切换的电解氧活性膜,对污染物具有可切换的选择性,用于净化水
Lie Liu1, Huachun Lan1, Yuqi Cui1
1Center for Water and Ecology, State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China.
Environmental science & technology
|October 31, 2023
概括
这项研究引入了一种基于聚烯的新型膜,用于净化水. 这种智能膜有效地去除离子和有机污染物,并且可以自行清洁,为清洁水提供可持续的解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 环境科学 环境科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 膜技术对于净水至关重要,但由于有限的选择性,它难以分离小分子.
- 传统的膜往往缺乏效率,需要添加剂进行再生,这给环境和成本带来了挑战.
研究的目的:
- 开发一种基于聚烯的活性膜,具有可切换的多相关性,用于同时分离离子和有机污染物.
- 为了实现高过效率,透性和无添加剂再生,实现可持续的水净化.
主要方法:
- 制造一种基于多聚烯的活性膜,其中包含两性分子.
- 用可逆电势来捕获和释放污染物.
- 先进的表征技术,以阐明分离机制.
主要成果:
- 膜表现出高单通过效率 (>99%对于1-纳胺和Pb2+) 和高透率 (227 L/m2/h).
- 可切换的潜能使污染物有效释放,促进膜再生和没有添加剂的自我清洁.
- 该机制揭示了两性分子的潜在诱导的方向变化,使选择性疏水或静电相互作用成为可能.
结论:
- 开发的智能膜提供可控的小离子和有机分子的分离.
- 这项技术为先进的水净化和污染物清除提供了一个有希望的,可持续的方法.
相关概念视频
Potentiometry: Membrane Electrodes
596
Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at...
596
Ion Exchange
600
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
600
Electrolysis
26.6K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
26.6K
Redox Reactions
55.7K
Oxidation-reduction or redox reactions involve the transfer of electrons from one molecule or atom to another. When an atom gains an electron, another atom must lose an electron, meaning oxidation and reduction must occur together. Since the redox occurs in pairs, the atom that gets oxidized is also called the reducing agent or reductant, and the atom that is reduced is also called the oxidizing agent or oxidant. A straightforward way to remember the definitions of oxidation and reduction is...
55.7K
Balancing Redox Equations
52.4K
Electrochemistry is the science involved in the interconversion of electrical and chemical reactions. Such reactions are called reduction-oxidation, or redox reactions. These important reactions are defined by changes in oxidation states for one or more reactant elements and include a subset of reactions involving the transfer of electrons between reactant species. Electrochemistry as a field has evolved to yield sufficient insights on the fundamental principles of redox chemistry and multiple...
52.4K
Dialysis
709
Dialysis is a diffusion-based purification process that separates analyte molecules from a complex matrix. This is accomplished by allowing molecules in the solution to pass through a semipermeable membrane into a liquid on the other side. The membrane is usually made of cellulose acetate or cellulose nitrate, and the second liquid must be miscible with the solution. Ions (e.g., chloride or sodium) or organic molecules (e.g., glucose) can pass through the membrane pores, which generally have...
709


