对三甲胺乙四级化合物的方法验证和环境监测
Chris Sparham1, Moira Ledbetter1, Richard Cubberley1
1Safety & Environmental Assurance Centre, Unilever, Colworth Science Park, Sharnbrook, Bedfordshire, MK44 1LQ, United Kingdom.
Chemosphere
|November 1, 2023
概括
三甲胺四元化合物 (TEAQ) 在尼内河中进行了分析. 先进的LC/MS/MS方法量化了TEAQ在水和沉积物中的含量,揭示了污水处理后环境中的低度.
科学领域:
- 环境化学环境化学
- 分析化学 分析化学
- 环境科学 环境科学
背景情况:
- 三甲胺四元化合物 (TEAQ) 用于各种应用.
- 它们的环境命运和度,特别是个别同类物质的环境命运和度,尚未得到充分了解.
- 污水处理厂 (STP) 是TEAQ进入水生环境的潜在入口点.
研究的目的:
- 开发和应用一种可靠的分析方法,用于在环境矩阵中量化单个TEAQ同类物质.
- 为了确定Nene河和相关沉积物的TEAQ度.
- 评估TEAQ在Great Billing STP的污水处理过程中的去除效率.
主要方法:
- 开发一种液体染色学-双重质谱法 (LC/MS/MS) 方法与电喷射电离 (ESI).
- 从Nene河和STP流入/流出的水和沉积物样本的分析.
- 使用特征性TALLOW TEAQ标准量化十个TEAQ成分.
主要成果:
- 成功建立了一种新的LC/MS/MS方法,用于敏感的TEAQ测定.
- 在污水处理过程中,TEAQ化合物表现出高的去除率 (>97%的单,>99%的).
- 在Nene河水和沉积物中检测到TEAQ的低度,通常低于方法检测极限.
结论:
- 开发的分析方法允许在环境样本中可靠量化广泛的TEAQ同类物种.
- 污水处理大大降低了进入水环境的TEAQ度.
- 尼内河和沉积物中的TEAQ水平通常很低,这表明STP的有效去除.
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