在库伦流体中的宏观力量的变化场理论
Yury A Budkov1,2, Petr E Brandyshev1
1Laboratory of Computational Physics, HSE University, Tallinskaya st. 34, 123458 Moscow, Russia.
The Journal of chemical physics
|November 2, 2023
概括
这项研究将平均场理论扩展到包括离子静电相关性,推导应力张量和封闭库伦流体的离合压力公式. 这有助于在电解质中的带电壁的电极孔中建模机械应力.
科学领域:
- 理论物理 理论物理
- 物理化学 物理化学
- 电化学 电化学 电化学
背景情况:
- 之前的工作为封闭的流体建立了一个平均场形式主义.
- 了解静电相关性对于准确建模离子系统至关重要.
研究的目的:
- 通过结合离子的静电相关性来扩展平均场形式主义.
- 导出一个通用表达式,用于在裂纹状毛孔中的库伦流体的分离压力.
主要方法:
- 使用变量场理论框架和通用共变量方法.
- 导出一个总应力张量,包括一个额外的电场波动的术语.
- 应用机械平衡条件以获得分离压力.
主要成果:
- 导出了一个总应力张量,考虑静电相关性.
- 建立了一个关于库伦流体在裂纹状毛孔中的分离压力的一般表达式.
- 获得了一个不对称的表达式,用于在有非电气化的导电壁的毛孔中分离压力.
结论:
- 开发的理论为模拟电解质中带电壁的电极孔中的机械应力提供了基础.
- 这项工作超越了复杂的离子系统的平均场理论的局限性.
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