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Updated: Jul 11, 2025

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
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将一个分子催化剂工程化为三维金属共价有机框架,以实现高效的水氧化

Wang-Kang Han1, Yong Liu1, Jing-Dong Feng1

  • 1Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University Wuxi 214122 China zhiguogu@jiangnan.edu.cn.

Chemical science
|November 3, 2023
PubMed
概括

研究人员使用分子催化剂开发了新的3D金属共价有机框架 (MCOFs). 这些MCOF在水氧化方面表现出卓越的性能,为先进的清洁能源解决方案铺平了道路.

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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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