在二维α-In2Se3铁电中,域核化动力学和两极化-纹理依赖的电子特性
Yanan Lu1, Liqin Su1, Linghui Fang1
1College of Optical and Electronic Technology, China Jiliang University, 310018 Hangzhou, China. shuhaibo@cjlu.edu.cn.
Nanoscale
|November 3, 2023
概括
我们在二维 (2D) 铁电半导体中探索了原子尺度域切换,例如α-二 (α-In2Se3). 域结构显著改变电子属性,使得定制的设备性能.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 纳米技术 纳米技术
背景情况:
- 两维 (2D) 铁电半导体,以α-In2Se3为例,具有可切换的自发偏振和优良的光电子特性,使它们成为先进设备应用的前景.
- 2D α-In2Se3的电子传输和设备性能高度依赖于铁电域结构和极化纹理,但这些方面在原子层面仍未得到充分探索.
研究的目的:
- 在原子尺度上研究 α-In2Se3 铁电物的域核化动力学和偏振纹理依赖的电子性质.
- 阐明域切换对电子带结构和载波分布在α-In2Se3.3.中的影响.
主要方法:
- 利用了第一原则计算和一个新的域切换理论的组合.
- 分析了域核化,传播能量障碍,以及外部电场对域进化的影响.
- 在单层和多层α-In2Se3.3.两种域切换过程中检查了带隙,载波分布和电子结构的变化.
主要成果:
- 识别了三角形或脱落的形状,用于与扶手椅边界的反向域.
- 为域边界传播计算了一个~1.42 eV的能量屏障,可以通过外部电场来减少.
- 在域切换时观察到带间隙和载波分布的显著变化,导致多极化状态相比单极化状态的阻力增加.
- 在多层α-In2Se3中演示了一种层次切换机制,将电子结构从自补充的p-n连接器转换为II型半导体同质连接器.
结论:
- 提供了对α-In2Se3铁电中的原子级域切换机制的基本见解.
- 建立了域结构和可调节的电子/传输属性之间的相关性.
- 突出了设计α-In2Se3特性用于新型电子和光电子设备应用的潜力.
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