估计大气中沉积在一个大河流域使用的和同位素签名的大气中沉积
Chenjun Du1, Qingjun Guo2, Pengcheng Wu3
1Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing, 100101, China; University of Chinese Academy of Sciences, Beijing, 100049, China.
Chemosphere
|November 5, 2023
概括
在长江流域,形揭示了 (N) 沉积模式. 燃烧源对和酸盐沉积有很大影响,城市排放量增加.
科学领域:
- 环境科学 环境科学
- 生物地质化学生物地质化学
- 大气化学 大气化学
背景情况:
- 在高空间分辨率下评估大气 (N) 沉积流和来源是一项挑战.
- 脊髓性作为一种敏感的生物监测器,监测沉积.
- 了解沉积对于生态系统健康和环境管理至关重要.
研究的目的:
- 分析 (NH4+) 和 (NO3-) 沉积在长江流域的流量和主要来源贡献.
- 为了研究N沉积的空间变化,使用发性的N和delta15N特征.
- 从2006年到2019年,确定N沉积源的时间趋势.
主要方法:
- 横跨长江流域的密集的形样本收集.
- 在组织中分析 (N) 和稳定同位素 (delta15N) 标志.
- 建模以估计来自不同来源 (挥发,燃烧,化石燃料) 的N沉积流量和分配贡献.
主要成果:
- 观察到沉积的空间梯度 (9.6-34.0 kg ha-1 yr-1),在耕地和城市地区的度更高.
- 氨 (NH4+) 沉积量大约是酸盐 (NO3-) 沉积量的三倍.
- 与传统观点相反,燃烧源 (66.72%) 是NH4+沉积的较大贡献者,而不是挥发 (33.28%).
- 化石燃料燃烧占NO3沉积的占主导地位 (70.22%).
- 城市NH3挥发和化石燃料衍生的NOx排放在2006年至2019年之间增加.
结论:
- 燃烧源是长江流域沉积的关键驱动因素.
- 形可以有效地监测N沉积的空间和时间变化.
- 这些发现挑战了关于NH3排放来源的传统假设,并突出了城市排放日益增长的影响.
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