探索低温氧化对煤炭石质物理特征的影响
He Li1, Jieyan Cao1, Jiexin Lu1
1School of Resource, Environment and Safety Engineering, Hunan University of Science and Technology, Xiangtan, Hunan 411201, China.
ACS omega
|November 6, 2023
概括
低温氧化破坏了煤炭结构,增加了孔隙的发展,并触发了自发燃烧. 这一过程随着温度的上升而加剧,导致毛孔堵塞.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 采矿工程 采矿工程 采矿工程
背景情况:
- 低温氧化是煤炭自燃的主要原因之一.
- 氧化无可挽回地损坏了煤的孔隙和断裂结构,促进了进一步的氧气进入.
研究的目的:
- 研究低温氧化过程中煤矿孔隙和裂结构的演变.
- 了解温度如何影响这些结构变化及其对氧气透的影响.
主要方法:
- 吸附分析以描述孔隙结构.
- 扫描电子显微镜 (SEM) 用于可视化微观结构变化.
- 超声波测试以评估裂的发展和传播.
主要成果:
- 氧化促进了微孔的形成和中孔和大孔的发展.
- 温度上升会放大氧化效应,尽管显著的孔腔形态变化并没有立即显现.
- 氧化导致煤颗粒在巨孔内堵塞或崩,堵塞程度随温度增加.
结论:
- 低温氧化显著改变了煤的孔隙结构,增强了自燃条件.
- 温度是控制氧化引起的损伤和孔隙堵塞程度的关键因素.
- 了解这些微观结构变化对于预测和防止煤炭自燃至关重要.
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