压力高解热对煤核化学和多孔结构的影响 煤核在深地下煤气化过程中的化学和多孔结构演变
Maofei Niu1, Lin Xin1,2, Weimin Cheng1,2
1College of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266590, China.
ACS omega
|November 6, 2023
概括
在700°C的高密度煤核的压力热解显著改变了热解气体的组成,增加了甲和. 较高的压力促进了长长的酸链的分解,并增强了半焦孔结构.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
背景情况:
- 来自煤炭热解的半焦炭对于地下煤炭气化至关重要.
- 了解压力热解是优化煤炭利用的关键.
研究的目的:
- 为了研究压力对从密集的煤核中产生的热解气体产生的影响.
- 阐明压力下的半焦炭中异形功能组和毛孔结构演变的机制.
主要方法:
- 在一个在700°C和1-3 MPa的轴炉中进行的压力热解实验.
- 使用N2吸附/脱附,SEM,FTIR和TGA-FTIR进行半焦炭和原煤的表征.
主要成果:
- 增加的压力显著改变了热解气体的组成,特别是CH4和H2含量.
- 甲主要来源于压力热解下的二次反应.
- 更高的压力促进了长长的形链的裂变 (降低了-CH2-/-CH3比率).
- 压力热解导致表面变形增加,半焦炭中孔隙结构更加丰富.
结论:
- 热解压力是影响气体产量和成分的关键因素.
- 压力热解增强了半焦炭中多孔结构的发展,潜在地提高了气化性能.
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