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在铜网上生长的石墨烯纳米墙

Abdeldjalil Reguig¹, Badri Vishal¹, Jasmin Smajic¹

¹Physical Science and Engineering Division, King Abdullah University of Science and Technology, Thuwal 23955-6900, Saudi Arabia.

|November 6, 2023

概括

晶圆尺度图案的石墨烯纳米墙 (GNW_s) 在使用低功率PECVD的铜网上生长. 这些疏水性GNW_s膜显示出改变表面湿的潜力,并作为离子电池中的阳极.

科学领域:

材料科学材料科学材料科学
纳米技术纳米技术
表面科学是一门学科.

背景情况:

石墨烯纳米墙 (GNW_s) 是在基板上垂直生长的石墨碳纳米板.
传统的GNW_s薄膜制造通常需要昂贵的清洁室程序,用于有图案的基板.
增强等离子体化学蒸汽沉积 (PECVD) 是GNW_s增长的一个常见技术.

研究的目的:

用一种经济有效的方法开发晶圆尺度图案GNW_s片.
描述这些有图案的GNW_s膜的结构,转移和特性.
探索GNW_s膜在表面修饰和能量储存中的应用.

主要方法:

使用低功率直流PECVD在铜网上种植GNW.
通过使用网状结构作为模板来实现晶圆尺度的图案.
描述包括分析薄膜形态,微观结构和湿性质. 应用测试包括离子电池阳极性能.

主要成果:

垂直对齐的GNW_s地毯 (~300nm高度) 已成功生长,复制了铜网格尺寸.
在相同条件下在铜上生长导致了有限的沉积.
转移的GNW_s膜表现出疏水性,并改变了SiO₂表面的湿行为.
在离子电池中,GNW_s膜证明了其作为C-on-Cu阳极的活性材料的实用性.

结论:

铜网上的低功率PECVD提供了一个可扩展和具有成本效益的途径,用于图案GNW_s膜.
由此产生的GNW_s膜具有独特的疏水特性,适合表面工程.
有图案的GNW_s膜对先进的应用有希望,包括离子电池阳极.

关键词:

离子电池是一种离子电池.碳纳米墙碳纳米墙铜铜铜铜的铜.石墨烯墙壁石墨烯墙壁防水涂层是防水涂层.增强等离子体化学蒸气沉积的化学蒸气沉积.垂直石墨烯是一种垂直石墨烯.

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