含氧功能组对可生物降解塑料的微机械行为及其在老化过程中形成微塑料的影响
Wenyi Huang1, Guoqiang Jiang1, Lidan Xie1
1Guangdong Key Laboratory of Environmental Pollution and Health, School of Environment, Jinan University, Guangzhou 510632, China.
Journal of hazardous materials
|November 8, 2023
概括
可生物降解塑料 (BPs) 迅速产生有害的微塑料 (MPs). 监测微机械性质可以早期检测微塑料的形成,揭示环境风险.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
背景情况:
- 可生物降解塑料 (BPs) 很容易形成微塑料 (MPs),造成环境问题.
- 早期检测MP形成具有挑战性,特别是通过监测含氧功能群.
- 在塑料老化过程中,演变的功能组和微机械特性之间的联系还没有得到充分研究.
研究的目的:
- 研究老化过程中BP和不可降解塑料的物理化学变化.
- 探索含氧功能组与微机械性质之间的关系.
- 评估与BP相关的早期MP形成和环境风险.
主要方法:
- 在人造海水,土壤和空气中比较BP和不可降解塑料的老化.
- 物理化学性质的分析,包括微机械性质和表面特征.
- 使用了诸如FTIR,2D-COS,AFM和拉曼光谱等光谱技术.
主要成果:
- 空气老化引起了最显著的氧化,特别是在BP中.
- 碳基的积累增加了微机械性能和表面脆性,加速了MP的形成.
- 由于含氧组增加了表面粘附度和粗度,凸显了BP的环境风险.
结论:
- 微机械性能测试可以作为预测微塑料形成的早期指标.
- 与可生物降解塑料相关的环境风险,特别是它们的MP生成,是显著的,需要注意.
- 了解早期降解机制对于开发更安全的塑料替代品至关重要.
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