在各种环境,食品和材料复杂矩阵中使用冷蒸汽生成高分辨率连续源高分辨率管原子吸收光谱法方法统一的操作条件来确定
Lucia Chirita1,2, Eniko Covaci1,2, Michaela Ponta1,2
1Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, Arany Janos 11, 400028 Cluj-Napoca, Romania. tiberiu.frentiu@ubbcluj.ro.
Analytical methods : advancing methods and applications
|November 9, 2023
概括
一种新的方法可以准确地确定食品,环境材料和塑料等各种样本中的总,使用冷蒸汽生成原子吸收光谱法. 这种经过验证的技术为分析提供了高灵敏度和精度.
科学领域:
- 分析化学 分析化学
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
背景情况:
- 准确确定总 (Hg) 对环境监测和人类健康风险评估至关重要.
- 现有的方法可能会面临复杂的矩阵和干扰的挑战.
- 需要一种多功能且经过验证的分析方法来实现广泛的应用.
研究的目的:
- 开发和验证一种广泛适用的分析方法,用于总的测定.
- 评估各种矩阵的样品制备和操作条件.
- 根据既定监管要求评估方法的性能.
主要方法:
- 冷蒸汽生成与高分辨率连续源石英管原子吸收光谱学 (CV-GFAAS) 相结合.
- 对食品,环境和 (生物) 聚合物样本进行评估的统一衍生和测量条件.
- 方法根据EURACHEM,EC决定和AOAC指南进行验证.
主要成果:
- 达到了低检测极限:0.064μg L-1 (水),0.014 mg kg-1 (环境),和0.009 mg kg-1 ((生物) 聚合物材料).
- 在各种矩阵中证明了认证参考材料的高回收率 (102 ± 20%).
- 展示了良好的精度 (4.215.0%) 和不受非光谱干扰.
结论:
- 开发的CV-GFAAS方法对于总的确定具有敏感性,精确性和广泛适用性.
- 该方法符合对常见矩阵的严格监管要求 (EC决定,AOAC).
- 这种技术为复杂的现实世界样本中的分析提供了可靠的工具.
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