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Updated: Jul 11, 2025

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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一个可隔离的基离子阳离子,具有2中心3电子的π键,没有明确定义的σ键

Yanbo Mei1,2, Xiaodan Chen3, Rui Wei1

  • 1Department of Chemistry and Research Center for Chemical Biology and Omics Analysis, College of Science, Southern University of Science and Technology, Shenzhen, 518055, China.

Angewandte Chemie (International ed. in English)
|November 9, 2023
PubMed
概括

研究人员合成了一种新型的激素离子,在平面Si2P2环中具有罕见的2中心-3电子 (2c3e) π键. 这一突破性的发现为含有和的化合物中不寻常的结合提供了新的见解.

关键词:
2 中心 3 电子 π 键化学结合是一种化学结合.DFT 计算方法的计算方法主群组元素 主群组元素激素阳离子 激素阳离子

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