通过真空紫外相对二氧化的照片-anammox
Wenzhe Liu1, Baiyang Chen1, Yang Yang1
1State Key Laboratory of Urban Water Resource and Environment, Shenzhen Key Laboratory of Organic Pollution Prevention and Control, Harbin Institute of Technology, Shenzhen 518055, China.
Journal of hazardous materials
|November 9, 2023
概括
这项研究引入了一种新的光诱导的anammox技术,使用UV/VUV/来有效地从废水中去除氨 (NH4+) 和总 (TN). 在无氧条件下,该过程迅速将NH4+降解为气 (N2).
科学领域:
- 环境化学环境化学
- 水处理技术水处理技术
- 光催化作用的光催化
背景情况:
- 过度的氨 (NH4+) 排放会导致肥沃化,并威胁到水的可持续性.
- 传统的anammox工艺需要长时间的微生物培养和熟练的操作,限制了它们的应用.
- 需要快速,高效和强大的方法来去除氨和总 (TN).
研究的目的:
- 提出和验证一种光诱导的anammox技术,用于从水中去除NH4+和TN.
- 在无毒条件下研究UV/真空UV (VUV) /工艺的效率和影响因素.
- 阐明降解途径并确定涉及去除的关键反应物种.
主要方法:
- 使用UV/VUV光和的组合对含有NH4+的水进行无氧处理.
- 在10分钟内优化Cl/N质量比和评估工艺性能.
- 分析气 (N2) 作为主要降解产物,并量化反应性物种 (RNS) 和反应性物种 (RCS).
主要成果:
- 在Cl/N质量比为5:1的情况下,在10分钟内达到66.8%的10mg-N/LNH4+和57.8%的TN减少.
- 已确认气 (N2) 是主要产品,溶氧 (DO) 度为2.0mg/L.
- 确定了RNS (42.5%) 和RCS (57.5%) 作为NH4+转化的主要驱动因素;TN去除在不同的pH,NH4+度,化物和硫酸盐水平上是稳健的,但对DO和二碳酸盐敏感.
结论:
- 无氧VUV/UV/工艺证明了 NH4+ 和 TN 除去的高效率和稳定性.
- 这项技术为传统方法提供了一个有希望的替代方案,绕过了微生物培养和操作复杂性的局限性.
- 照相诱导的anammox方法为废水管理提供了快速有效的解决方案.
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