双金属MXene与定制的d频段作为可逆氧电池的高效电催化剂
Pengfei Liu1, Haoyang Xu1, Xinxiang Wang1
1College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, 1#, Dongsanlu, Erxianqiao, Chengdu 610059, Sichuan, PR China.
Journal of colloid and interface science
|November 10, 2023
概括
一种新的TiVC双金属MXene电催化剂显著提高了氧 (Li-O2) 电池的性能. 这种催化剂增强了氧氧还氧化动力学,使更高的放电能力和延长循环稳定性用于先进的能量存储.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 氧 (Li-O2) 电池具有较高的理论能量密度 (~3500 Wh kg-1).
- 缓慢的氧氧还氧化动力学阻碍了Li-O2电池的实际应用.
- 有效的电催化剂对于克服运动限制至关重要.
研究的目的:
- 为氧电池开发一种高效的电催化剂.
- 为了研究TiVC双金属MXene的催化机制.
- 为了提高Li-O2电池的电化学性能.
主要方法:
- 合成TiVC双金属MXene固体溶液.
- -O2电池的电化学性能测试.
- 实验和理论计算 (例如,DFT) 来阐明催化机制.
主要成果:
- TiVC MXene表现出增强的电子脱离和加强LiO2中间体的吸附.
- 通过表面吸附通路形成膜状Li2O2,确保电极与产品的完全接触.
- 基于TiVC的Li-O2电池实现了大放电容量 (12780 mAh/g) 和422个循环在300 mA g-1.
结论:
- TiVC 双金属 MXene 作为 Li-O2 电池的高效电催化剂.
- 催化剂通过优化中间吸附和电荷转移来促进氧氧还氧反应.
- 这项工作表明了开发高性能-O2电池的有希望的战略.
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