使用基于铁的电凝过程从皮革工业的废水中去除:实验;动力学;异热和经济研究
Heba A El-Gawad1, Gamal K Hassan2, Karim M Aboelghait3
1Department of Engineering Mathematics and Physics, Higher Institute of Engineering, El- Shorouk Academy, Cairo, Egypt.
Scientific reports
|November 10, 2023
概括
电凝疗法有效地使用低成本的铁电极从皮革厂的废水中去除. 这种方法实现了98.76%的消除,为危险工业废物提供了具有成本效益的解决方案.
科学领域:
- 环境工程 环境工程
- 水处理技术水处理技术
- 电化学 电化学 电化学
背景情况:
- 来自工业工艺的化合物由于其毒性,致变性,致性和致癌性而构成重大环境和健康风险.
- 现有的化学处理方法是有效的,但会产生大量的污泥,并且往往不具有成本效益.
- 需要可持续和经济的替代方法来处理含的工业废水,特别是来自皮革厂的废水.
研究的目的:
- 研究使用低成本铁板电极的电凝疗法的有效性,用于处理污染的制厂废水.
- 为了优化操作参数,最大限度地提高去除效率.
- 评估电凝过程的经济可行性和动力性能.
主要方法:
- 使用铁板电极进行了电凝试验.
- 关键的操作参数包括初始度,电压,电极数,操作时间,动速度和电流密度被系统地变化和研究.
- 评估了去除的效率,并进行了动力学研究 (第一阶反应,兰木尔异温). 使用统计回归,开发了一个预测相关性.
主要成果:
- 在优化的条件下 (15V,0.4 mA/cm2,200rpm,330 ppm,8个铁电极,3小时),的消除达到98.76%.
- 该工艺证明了低铁阳极消耗 (0.99 gm/L),最小的功耗 (0.0143 kW-h/L) 和具有竞争力的运营成本 (160 EGP/kg消除).
- 动力学分析显示,该反应与第一阶反应模型 (97.99%的相关性) 和兰格穆尔等热量 (R2:99.99%) 非常一致. 一个预测模型实现了97.97%的准确性.
结论:
- 使用铁电极进行电凝,是一种高效且具有成本效益的技术,可以从制厂的废水中去除.
- 优化的工艺实现了几乎完全的去除,证明了其工业应用的潜力.
- 开发的预测相关性和动力学模型为过程设计和在现实世界制环境中扩展提供了有价值的工具.
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