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相关概念视频

Colloids03:22

Colloids

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Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
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Colloidal precipitates01:09

Colloidal precipitates

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The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
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Lipids are large molecules that are generally not water-soluble. Since most of the digestive enzymes in the human body are water-based, there are specific steps the body must take to break down lipids and make them available for use.
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The experimental conditions in a gravimetric analysis should be optimized to maximize the particle size and purity of the obtained precipitate. Ideally, the concentration of the precipitating reagent should be low with effective stirring to maintain low relative supersaturation for the growth of large crystals. In homogeneous precipitation, the precipitant is slowly generated by a chemical reaction in the solution to avoid local reagent excesses. For example, urea decomposes gradually to...
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自发乳化:局部过程的解.

Monicka Kullappan, Wes Patel, Manoj K Chaudhury

    Langmuir : the ACS journal of surfaces and colloids
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    概括
    此摘要是机器生成的。

    这项研究显示,自发乳化涉及局部表面活性剂和水转移,导致乳液逆转. 添加剂可以通过抑制转移来阻止这一过程.

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    科学领域:

    • 物理化学 物理化学
    • 体科学 体科学 体科学
    • 接口现象 接口现象

    背景情况:

    • 尽管进行了热力学研究,但自发乳化机制仍然不清楚.
    • 了解局部过程对于控制乳液形成和逆转至关重要.

    研究的目的:

    • 在自发乳化过程中调查表面活性剂和水转移的局部过程.
    • 阐明水在油到油在水乳液逆转的机制.

    主要方法:

    • 紫外线 (UV) 光谱学.紫外线 (UV) 光谱学.
    • 没有平衡的分子动力学模拟.
    • 对乳液液滴扩散和成分度波动的分析.

    主要成果:

    • 观察到表面活性剂和水从水相向油相的局部转移.
    • 乳液逆转在突破相位边界时突然发生,可能涉及爆炸和碎片组装.
    • 观察到乳液滴的快速扩散和界面度波动.

    结论:

    • 自发乳化是由局部接口运输和相位边界动态驱动的.
    • 混合溶剂放大了乳化,而特定的添加剂可以阻止该过程.
    • 结果为控制乳液稳定性和形成提供了洞察力.