通过H核磁共振探测到柱状热岩中的纳米封闭水
Marina G Shelyapina1, Denis Y Nefedov1, Anastasiia O Antonenko1
1Faculty of Physics, Saint Petersburg State University, 7/9 Universitetskaya Nab., Saint Petersburg 199034, Russia.
International journal of molecular sciences
|November 14, 2023
概括
通过使用质子核磁共振 (NMR) 来研究等级性热岩中的水动力学. 结果显示了复杂的行为,有明显的结,旋转和转移运动,受孔结构的影响.
科学领域:
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
- 纳米技术纳米技术
背景情况:
- 水在多孔材料中的限制会影响其性能.
- 层次式热石为分子相互作用提供独特的孔隙结构.
- 了解水动力学对于催化和分离过程至关重要.
研究的目的:
- 为了研究水的分子动力学,限制在等级的岩 (mordenite和ZSM-5).
- 为了确定不同水分子运动的激活能量.
- 阐明层次性孔隙结构在水扩散中的作用.
主要方法:
- H核磁共振 (NMR) 光谱学. 核磁共振 (NMR) 光谱学. 核磁共振 (NMR) 光谱学. H核磁共振 (NMR) 光谱学.
- 1H旋转格的放松时间测量.
- 从173K到298K的温度依赖性研究.
主要成果:
- 观察到水的复杂行为,包括结,快速旋转和转移运动.
- 确定了三种不同的过程,具有不同的激活能量.
- 在等级的热石中,转移运动激活能量低于无序的多孔材料.
结论:
- 在等级性热岩中,水的扩散是由中孔和微孔之间的相互作用决定的.
- 微孔在确定水分子的转换运动方面发挥着主导作用.
- 层次性孔隙结构显著影响水的动态.
相关概念视频
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