第14组氧化物具有独特的电气性质:SiO,SiO和SnO
Antonio Nuno Guerreiro1,2, Ilidio B Costa2,3, Antonio B Vale2,3
1Engineering Physics Department, Engineering Faculty, University of Porto, 4200-465 Porto, Portugal.
International journal of molecular sciences
|November 14, 2023
概括
像SiO2,SiO和SnO2这样的14组氧化物具有类似的工作功能. SiO 显示出独特的电气性质,表明了先进的电子设备和异质连接的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 表面科学是一门学科.
背景情况:
- 14组氧化物在各种行业中至关重要,包括电子和储能.
- 了解它们的电特性是开发新型设备的关键.
研究的目的:
- 模拟并通过实验确定SiO2,SiO和SnO2的工作功能和电特性.
- 研究这些氧化物在电子应用中的潜力,特别是SiO.
主要方法:
- 扫描凯尔文探测器 (SKP) 用于实验工作的功能确定.
- 电子带结构,电子定位函数和载体移动性的模拟.
- 氧化物金属异质连接的分析.
主要成果:
- SiO2,SiO和SnO2具有类似的工作功能.
- SiO显示Poole-Frenkel排放或陷辅助道和表面等离子体极子传播.
- SnO2显示出作为具有高载体流动性的n型半导体的潜力.
- SiO2 作为一种稳定的绝缘体,与金属的相互作用较低.
结论:
- SiO表现出与等离子体和元材料设备相关的独特现象.
- 这些发现提供了对氧化物-金属异质连接和在半导体和储能领域的潜在应用的见解.
- 不同的氧化物为量身定制的设备应用提供不同的特性.
相关概念视频
Properties of Transition Metals
26.0K
Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
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Noble Gases
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The elements in group 18 are noble gases (helium, neon, argon, krypton, xenon, and radon). They earned the name “noble” because they were assumed to be nonreactive since they have filled valence shells. In 1962, Dr. Neil Bartlett at the University of British Columbia proved this assumption to be false.
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Alkali Metals
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Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
Table 1: Properties of the alkali metals
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Ions and Ionic Charges
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In ordinary chemical reactions, the nucleus — which contains the protons and neutrons of each atom and thus identifies the element — remains unchanged. Electrons, however, can be added to atoms by transfer from other atoms, lost by transfer to other atoms, or shared with other atoms. The transfer and sharing of electrons among atoms govern the chemistry of the elements. During the formation of some compounds, atoms gain or lose electrons to form electrically charged particles called...
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Ionic Bonding and Electron Transfer
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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
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Halogens
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Group 17 elements, known as halogens, are nonmetals. At room temperature, fluorine and chlorine are gases, bromine is a liquid, and iodine a solid. Astatine is a highly unstable radioactive element, so currently, most of its properties are unknown due to its short half-life. Tennessine is a synthetic element also predicted to be in this group.
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