微气泡氧化为Fe2+从盐酸中去除矿石矿石溶液
Ziyang Xu1,2, Yu Wang1,2, Boyuan Zhu1,2
1National Engineering Research Center of Green Recycling for Strategic Metal Resources, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China.
Materials (Basel, Switzerland)
|November 14, 2023
概括
微气泡通风有效地去除了酸出酸的铁 (II) 杂质. 这种新的金工艺实现了超过99%的氧化效率,增强了金属的分离.
科学领域:
- 金工程 金工程 金工程
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 使用盐酸浸出处理的后期矿石加工会产生含有大量Fe2+杂质的浸出物.
- 有效地去除Fe2+对于随后的金属分离和净化至关重要.
研究的目的:
- 为了研究微泡气化对酸化物中Fe2+氧化的微泡气化功效.
- 优化工艺参数,了解Fe2+氧化过程中的质量转移和动力学方面.
主要方法:
- 使用微泡气化技术氧化Fe2+离子.
- 系统地改变通风孔,速度,氧气流速,pH值和温度.
- 分析质量转移系数和进行动力学研究.
主要成果:
- 在优化条件下 (0.45μm光圈,500rpm,0.4L/min O2,pH3.5,75-85°C) 实现了>99%的Fe2+氧化.
- 微气泡通风显著增加了氧气质量转移系数,达到0.051 s-1.
- 证实了Fe2+氧化过程的自我催化特性,其明显激活能量为399kJ/mol.
结论:
- 微气泡通风是一种高效的方法,可以从岩漏物中去除Fe2+.
- 氧化过程受到pH的影响,化学反应在pH3.5以下占主导地位,化学反应和溶解控制在pH3.5以上.
- 这项研究为优化涉及岩矿石的水力金工艺提供了宝贵的见解.
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