氨-氨联合激活:促进阿苏里特的硫化及其对酸盐吸附的影响
Chao Su1, Dianwen Liu1, Jinpeng Cai1
1State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Yunnan Key Laboratory of Green Separation and Enrichment of Strategic Metal Resources, Faculty of Land Resources Engineering, Kunming University of Science and Technology, Kunming 650093, China.
合并的氨胺盐通过改善硫化,增强青的漂浮. 这种新的方法通过更好的硫化铜形成和酸盐吸附来促进矿物回收.
科学领域:
- 矿物加工 矿物加工
- 表面化学 表面化学
- 材料科学 材料科学 材料科学
背景情况:
- 硫化是铜氧化物矿物浮动的关键.
- 亚苏里特 (氧化铜矿物质) 需要有效的硫化才能进行分离.
- 现有的方法在优化硫化效率方面面临着挑战.
研究的目的:
- 调查使用联合胺盐用于增强青酸盐硫化.
- 为了评估氨胺联合激活对硫化-酸盐漂浮的影响.
- 为了阐明改善漂浮性能背后的机制.
主要方法:
- 进行了浮动试验,以评估矿物回收.
- 飞行时间二次离子质谱 (ToF-SIMS) 分析了表面成分.
- 感应合等离子光学发射光谱学 (ICP-OES) 的量化元素.
- 场发射扫描电子显微镜与能量分散光谱学 (FESEM-EDS) 检查了微观结构.
- 原子力显微镜 (AFM),X射线衍射 (XRD) 和紫外线可见光谱 (UV-vis) 提供了进一步的表征.
主要成果:
- 与单盐激活相比,氨胺联合激活显著提高了亚苏里特的浮性.
- 随着联合激活,漂浮恢复增加了超过4个百分点.
- 协同激活促进了在青石表面上矿 (硫化铜) 的形成和稳定.
- 增强的硫化铜生成促进了酸盐吸附的增加.
结论:
- 合并的氨胺盐为亚苏里特硫化提供了一种优越的方法.
- 协同效应涉及pH缓冲 (氨) 和铜复合 (氨).
- 这种方法增强了硫化铜的形成和粘附,提高了漂浮效率.
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