提高3D打印PVDF的压电特性,使用并发的扭转剪切应变
Pu Han1, Alireza Tofangchi2, Derek Carr2
1Ira A Fulton Schools of Engineering, Arizona State University, Tempe, AZ 85212, USA.
Polymers
|November 14, 2023
概括
这项研究使用3D打印并添加扭转剪切应变,将聚乙烯二化物 (PVDF) 的压电性能提高了400%. 这种方法控制了聚合物链对齐和结晶性,以提高材料性能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 增材制造 增材制造 增材制造
背景情况:
- 基于挤出的3D打印在聚合物中引入剪切菌株,影响其性能.
- 聚乙烯二化物 (PVDF) 在受到剪切诱导的聚合物链拉伸时表现出增强的结晶性和压电性.
研究的目的:
- 为了研究3D打印过程中额外的扭转剪切应变对PVDF压电特性的影响.
- 探索剪切应变,晶相形成和3D打印PVDF中的压电增强之间的相关性.
主要方法:
- 使用基于挤出的3D打印与旋转的喷嘴传授连续的扭转剪切应变.
- 使用富里埃变换红外光谱法 (FTIR) 描述了结晶β相的形成.
- 量化了压电性质的增强.
主要成果:
- 在3D打印的PVDF的压电特性中实现了400%的增强.
- 证明了连续的扭转剪切应变促进了结晶β相的形成.
- 建立了喷嘴旋转速度和β相形成程度之间的直接关系.
结论:
- 工艺中的切割应变是一种可行的方法,用于控制3D打印材料中的聚合物链对齐和晶体相.
- 这种方法为开发具有定制压电性质的先进3D打印聚合物和复合材料提供了新的途径.
- 该研究强调了增材制造在通过受控机械刺激来设计材料特性方面的潜力.
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