坚固的界面粘附使得极其耐用的灵活超级电容器成为可能
Lanlan Feng1, Guofa Mi1, Xinlei Shi2
1School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, China.
ACS applied materials & interfaces
|November 14, 2023
概括
工程化水凝聚合物电解质 (HPEs) 增强了接口粘附,创造了耐用的固态超级电容器 (SC). 这些柔软的,自粘HPE在极端曲和扭曲下保持性能,即使在低温下也是如此.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 聚合物科学 聚合物科学
背景情况:
- 表面空隙和分层降解固态三明治超级电容器 (SCs) 在变形过程中由于粘合力差而降解.
- 开发强大的接口对于灵活的储能设备至关重要.
研究的目的:
- 为了设计一个水凝聚合物电解质 (HPE) 增强的接口粘附性耐用性SCs.
- 研究软,坚固和自粘HPE在重复变形下对SC性能的影响.
主要方法:
- 合成了一种自我交叉链接的聚N-基乙烯胺) /H3PO4 (PHEAA/H3PO4) HPE.
- 测量了HPE和聚氨改性碳布电极之间的界面粘附 (Γ).
- 在曲和扭曲下评估了组装的SC的电化学性能和耐用性,包括低温性能.
主要成果:
- 设计的HPE与电极实现了556J/m2的接口粘附.
- 超级电容器在10万个曲周期后保持了94.14%的电容,在扭转后保持了93.62%.
- SCs在低温下表现出色,在 -20 °C下经过10,000个曲周期后保持98.03%的电容.
结论:
- 接口粘附工程对于创建耐变形SCs至关重要.
- 开发的软,坚固和自粘HPE策略显著提高了SC的耐用性和低温性能.
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