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Updated: Jul 11, 2025

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
09:37

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

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通过与孤立的内部醇丰富的 Al-IDM-1 基酸纳米薄膜将合成气促进烯酸

Jie Tuo1,2,3, Yaqi Fan4, Yan Wang5

  • 1Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, North Zhongshan Rd. 3663, 200062, Shanghai, China.

Angewandte Chemie (International ed. in English)
|November 14, 2023
PubMed
概括

一种具有独特孔隙结构的新型Al-IDM-1焦化物显著改善了合成气转化为烯酸,达到85%的C2-6烯酸选择性和高烯酸/烯酸比率14. 这种材料增强了烯和丁烯的选择性,这对于有价值的化学品生产至关重要.

关键词:
美国IDM-1热带石内部的西兰醇.烯是一种烯.综合气转化转换公司

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Author Spotlight: Standardizing the Development of Amine-Based Silica Composites as CO2 Adsorbents for Direct Air Capture08:00

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Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide

Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

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Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
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