在宽带间隔半导体二维碳化物板中实现坚固且环境稳定的室温铁磁
Yong Wang1,2, Wei Xu3, Lin Fu4
1Wide Bandgap Semiconductor Technology Disciplines State Key Laboratory, School of Microelectronics, Academy of Advanced Interdisciplinary Research, Xidian University, Xi'an 710071, China.
ACS applied materials & interfaces
|November 14, 2023
概括
在二维二氧化碳化物 (CN) 片中,通过用进行兴奋剂,实现了强大的室温铁磁性. 这一突破使得稳定,耐空气的自旋电子设备具有下一代电子产品的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 纳米技术 纳米技术
背景情况:
- 二维碳化物 (CN) 片具有宽带间隙 (3.06 eV) 和弱自旋轨道合,使它们对自旋电子具有吸引力.
- 在2D材料中实现强大的室温铁磁性 (FM) 和环境稳定性仍然是一个重大挑战.
研究的目的:
- 为了研究二维碳化物合的潜力,以实现稳定的室温铁磁性.
- 探索对所观察到的磁性质负责的潜在机制.
主要方法:
- 使用磁光学克尔效应,霍尔装置测量,X射线磁圆二元化和磁力显微镜进行实验性表征.
- 通过详细的描述进行结构分析.
- 使用密度函数理论 (DFT) 计算进行理论验证.
主要成果:
- 证明了强大的室温铁磁性 (FM),其基里温度 (TC) 为400K,和磁化 (Ms) 为2.91emu/g.
- 展现出出色的空气稳定性,Ms保持稳定超过6个月.
- 证实了Co-doped CN保留了其半导体特性,并确定了单原子Co协调,缺陷和C-C共价键.
结论:
- 联合合的2D CN表现出有希望的室温铁磁性质,具有高稳定性.
- DFT计算表明,C-C债券诱导载体旋转极化,调解长距离磁性排序的磁性交换.
- 这些发现为开发基于半导体的二维宽带间隙自旋电子设备提供了基础.
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