化是众所周知的,但它是否也得到了充分的理解?
1Laboratory of Physical Chemistry, Eindhoven University of Technology, Het Kranenveld 14, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
Chemical reviews
|November 14, 2023
概括
对于不连续的相位过渡,如融,缺乏统一的理论. 本综述探讨了固态缺陷理论和表面效应,为融现象提供了视角.
科学领域:
- 物理 物理学 物理
- 材料科学 材料科学 材料科学
- 热力学是一种热力学.
背景情况:
- 连续相位过渡已经建立了重新规范化组理论.
- 不连续的相变,包括化,缺乏一般的理论框架.
- 现有的融化理论往往侧重于特定的固体缺陷或单相模型.
研究的目的:
- 审查并提供各种融理论和模型的视角.
- 讨论融过程中缺陷和表面的作用.
- 检查压力和材料类型对化的影响.
主要方法:
- 审查现有的化的单相理论和模型.
- 分析固体中缺陷机制 (空隙,间隙,位移) 的分析.
- 大量与表面介导的融化现象的讨论.
主要成果:
- 没有一个单一的,被普遍接受的理论能够解释化.
- 固体中的缺陷在不同的融模型中起着至关重要的作用.
- 表面效应显著影响热力学融.
结论:
- 融化仍然是一个复杂的现象,没有一个全面的理论.
- 了解融需要考虑各种机制,包括缺陷和表面.
- 需要进一步的研究来开发一个统一的框架不连续的相位过渡.
相关概念视频
Phase Transitions: Melting and Freezing
12.4K
Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
12.4K
Phase Changes
4.3K
Phase transitions play an important theoretical and practical role in the study of heat flow. In melting or fusion, a solid turns into a liquid; the opposite process is freezing. In evaporation, a liquid turns into a gas; the opposite process is condensation.
A substance melts or freezes at a temperature called its melting point and boils or condenses at its boiling point. These temperatures depend on pressure. High pressure favors the denser form of the substance, so typically, high pressure...
A substance melts or freezes at a temperature called its melting point and boils or condenses at its boiling point. These temperatures depend on pressure. High pressure favors the denser form of the substance, so typically, high pressure...
4.3K
Heating and Cooling Curves
22.9K
When a substance—isolated from its environment—is subjected to heat changes, corresponding changes in temperature and phase of the substance is observed; this is graphically represented by heating and cooling curves.
For instance, the addition of heat raises the temperature of a solid; the amount of heat absorbed depends on the heat capacity of the solid (q = mcsolidΔT). According to thermochemistry, the relation between the amount of heat absorbed or released by a substance, q, and its...
For instance, the addition of heat raises the temperature of a solid; the amount of heat absorbed depends on the heat capacity of the solid (q = mcsolidΔT). According to thermochemistry, the relation between the amount of heat absorbed or released by a substance, q, and its...
22.9K
Phase Transitions: Sublimation and Deposition
17.2K
Some solids can transition directly into the gaseous state, bypassing the liquid state, via a process known as sublimation. At room temperature and standard pressure, a piece of dry ice (solid CO2) sublimes, appearing to gradually disappear without ever forming any liquid. Snow and ice sublimate at temperatures below the melting point of water, a slow process that may be accelerated by winds and the reduced atmospheric pressures at high altitudes. When solid iodine is warmed, the solid sublimes...
17.2K
Bonding in Metals
47.4K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”.
47.4K
Recrystallization: Solid–Solution Equilibria
1.1K
Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
1.1K


