一个Ti3C2T@PANI核心外异构组装成一个3D多孔水凝作为高能超级电容器的独立电极
Peng Liao1, Jian Song1, Zenghui Qiu1
1College of Mathematics & Physics, Beijing University of Chemical Technology, Beijing 100029, China. qiuzh@buct.edu.cn.
Physical chemistry chemical physics : PCCP
|November 15, 2023
概括
这项研究引入了一种新的3D Ti3C2Tx@PANI-RGO超级电容液凝. 该材料克服了Ti3C2Tx的自我补充,增强了离子传输和电化学性能,用于先进的能量存储.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 纳米技术 纳米技术
背景情况:
- 碳化 (Ti3C2Tx) MXenes由于导电性和表面积,显示出储能方面的前景.
- 3C2Tx层的自我补充阻碍了离子运输,限制了超级电容器电极的性能.
- 间隔策略对于增加层间间距和改进基于MXene的设备至关重要.
研究的目的:
- 为了合成一个层次化的Ti3C2Tx@PANI降解石墨烯氧化物 (RGO) 异构水凝.
- 为了改善超级电容应用,提高Ti3C2Tx的层间距并减轻Ti3C2Tx的自我重新堆叠.
- 为了创建一个无粘合剂的电极,具有卓越的电化学性能.
主要方法:
- 聚氨酸 (PANI) 纳米棒通过氨酸单体聚合在Ti3C2Tx纳米板上生长.
- 使用石墨烯氧化物 (GO) 辅助的热水战略,形成3D多孔框架.
- 由此产生的Ti3C2Tx@PANI-RGO异构水凝作为超级电容电极进行了表征和测试.
主要成果:
- Ti3C2Tx@PANI-RGO异构水凝在1Ag-1时表现出高特异电容301.0Fg-1.
- 电极表现出极好的稳定性,在10,000个周期内保持90.74%的电容.
- 在504.7 W h kg-1的功率密度下,达到44.6 W h kg-1的最大能量密度.
结论:
- 开发的3D异构水凝有效地解决了Ti3C2Tx自复位问题.
- 协同效应和多孔结构导致电导率和电化学活性提高.
- 该战略为设计用于储能的基于MXene的先进混合材料提供了一条新的途径.
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