光诱导吸收光谱学 (PIAS) 通过在酸性溶液中的WO3光电极对水和氧化物的研究
James Johnston1, Christopher O'Rourke1, Andrew Mills1
1School of Chemistry and Chemical Engineering, Queens University Belfast, Stranmillis Road, Belfast, BT9 5AG, UK. jjohnston497@qub.ac.uk.
Physical chemistry chemical physics : PCCP
|November 15, 2023
概括
这项研究研究了使用WO3光电极的水和氧化. 光诱导吸收光谱学揭示了水和氧化物的不同反应顺序,表明了不同的机制.
科学领域:
- 光催化作用的光催化
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
背景情况:
- 三氧化物 (WO3) 是氧化反应的有前途的光电极材料.
- 了解水和的氧化机制对于开发高效的光电化学系统至关重要.
- 之前的研究表明,WO3对水和氧化有不同的效率.
研究的目的:
- 为了阐明水和氧化在WO3光电极上的氧化机制.
- 为了确定两个氧化过程的光生成表面孔的反应顺序.
- 提出相关机制和关税决定步骤.
主要方法:
- 光诱导吸收光谱学 (PIAS) 与短暂光电流 (TC) 测量相结合.
- 线性扫描电压测量 (LSV) 和发生光子对电流效率 (IPCE) 测量.
- 在水性酸和化电解质中进行的电化学实验.
主要成果:
- 法拉戴克将水氧化为O2的效率大约为1.0.
- 法拉戴克将化物氧化为Cl2的效率大约为0.62.2.
- PIAS/TC数据显示,水氧化的依赖度为0.4级,化物氧化的依赖度大约为1级,对光生成的表面孔 ([h_s+]_ss).
结论:
- 不同的反应顺序表明WO3光电极上的水和氧化速度的不同决定步骤.
- 提出的机制解释了观察到的反应动力学.
- 这项研究为选择性氧化反应的WO3光电极的表面化学提供了基本的见解.
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