静态压力对地下水中微纳米泡臭氧化的托洛氧化效率的影响
Yuqin Mao1, Zeming Xie2, Dongsheng Shen2
1College of Biology and Environmental Engineering, Zhejiang Shuren University, Hangzhou, 310015, China.
Chemosphere
|November 15, 2023
概括
静态水压通过缩小气泡和增加基产生来增强微纳米泡臭氧化,用于地下水整治. 这提高了二氧化效率,显示了污染现场清理的前景.
科学领域:
- 环境化学环境化学
- 水处理技术水处理技术
- 氧化过程 氧化过程
背景情况:
- 微纳米泡臭氧化是有效的饮用水净化由于高质量转移率.
- 在地下水整治中的有限应用源于对静态压力对氧化效率影响的不清楚理解.
研究的目的:
- 通过使用臭氧微纳米气泡水,研究静态水压对二烯氧化效率的影响.
- 确定静态压力如何影响微气泡特性和基生成.
主要方法:
- 一个批量反应堆被用来应用不同的静态水压 (0.0到2.5米).
- 烯和溶解臭氧的初始度分别保持在1.00毫克L-1和0.68毫克L-1.
- 测量了微气泡直径,氧化率和反应速度.
主要成果:
- 增加静态水压从0.0到2.5米显著降低了平均微气泡直径 (62.3到36.0微米).
- 托卢烯氧化率从40.3%增加到58.7%,与基 (OH·) 的反应速率显著增加.
- 在静态压力下,酸显示出比p-xylen更强的氧化增强,证实了增加的OH·贡献.
结论:
- 静态水压通过促进OH·生成,积极影响地下水修复中的微纳米泡臭氧化效率.
- 该技术在处理污染的地下水方面具有前景,但在复杂的矩阵或极端pH条件下,效率可能会降低.
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