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Na+ 预间接的MoO3 微棒用于具有增强性能的水性/电池
Jiasheng Yue1, Shi Chen1, Yahui Wang1
1Beijing Key Laboratory of Environmental Science and Engineering School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China.
ACS applied materials & interfaces
|November 16, 2023
概括
预插曲增强了用于水性/电池 (AZSB) 的三氧化 (MoO3) 阴极. 这一战略提高了产能,稳定性和速度能力,克服了结构性退化问题.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 多层三氧化物 (MoO3) 显示出水性二次电池的潜力,因为它的理论容量很高.
- 然而,MoO3存在结构性降解和低于最佳的内在特性,限制了其实际使用.
研究的目的:
- 开发一种高性能阴极材料,用于水性/电池 (AZSBs),使用Na+预插入策略.
- 调查Na+预插曲对MoO3.3的结构,电子和电化学性质的影响.
主要方法:
- 纳+的预间隔策略可以合成Na0.25MoO3.3.
- 在AZSB中进行电化学性能测试 (容量,循环稳定性,速率能力).
- 实验测量和密度函数理论 (DFT) 计算,以了解属性调制.
主要成果:
- 该Na0.25MoO3阴极在1Ag-1时实现了251.1mAhg-1的可逆容量.
- 它表现出了出色的循环稳定性,在500个循环后保持了79.2%的容量,并且具有高速率能力 (121.5 mAh g-1在20 A g-1).
- DFT计算和实验数据证实,预间隔抑制结构崩,增强Na+插入,并改善放电潜力.
结论:
- +预插曲是一种有效的策略,用于为AZSBs创建强大的MoO3基阴极.
- 与原始的MoO3.3相比,修改后的MoO3表现出优越的电化学性能.
- 这项研究为开发水性能量存储系统的基于的先进阴极材料提供了见解.
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