引入TiO2,增强Ti的催化性能,用于二甲基以太的氧化
Guozhuang Cao1,2, Xiujuan Gao1, Faen Song1
1State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China. qdzhang@sxicc.ac.cn.
概括
将二氧化 (TiO2) 添加到二氧化 (SiO2) 中,可以提高二甲基以太 (DME) 氧化催化剂的性能. 优化的烧焦温度显著提高了二甲氧化甲 (DMM) 的产量.
科学领域:
- 材料科学 材料科学 材料科学
- 催化剂是一种催化剂.
- 表面化学 表面化学
背景情况:
- 二氧化 (SiO2) 的表面特性因添加二氧化 (TiO2) 而显著改变.
- 硫酸 (Ti(SO4) 2) 在SiO2上的分散受TiO2的影响,影响催化剂性能.
- 酸度和氧化还原特性是二甲基乙烯 (DME) 氧化催化剂活性中的关键因素.
研究的目的:
- 研究TiO2对SiO2表面特性和Ti(SO4) 2分散的作用.
- 了解Ti(SO4) 2分布,酸度,氧化还原特性和DME氧化催化剂性能之间的关系.
- 为了优化TiO2/SiO2催化剂的烧焦温度,以增强二氧化甲 (DMM) 的形成.
主要方法:
- 合成TiO2 / SiO2材料的合成.
- 表面性质的表征,包括酸度和Ti价值状态.
- 在DME氧化反应中评估催化剂性能.
- 对TiO2/SiO2催化剂的化温度的优化.
主要成果:
- 化温度影响TiO2/SiO2的表面基含量,控制Ti(SO4) 2的分散.
- Ti ((SO4) 2) 的分布导致了不同的酸位和Ti价值状态.
- Ti(SO4) 2 / TS-400 °C催化剂表现出最多的弱酸位点和有利的Ti3+/Ti4+比率.
- 与Ti(SO4) 2 / SiO2.2相比,DMM形成在优化Ti(SO4) 2 / TS-400 °C催化剂的情况下从14.4%增加到82.6%.
结论:
- SiO2的TiO2修饰显著影响DME氧化的催化剂特性.
- 化温度是通过控制Ti分散和表面化学来调整催化剂性能的一个关键参数.
- 优化的TiO2 / SiO2催化剂在DMM生产中表现出卓越的效率.
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