将臭氧和超声波技术结合起来,在拜耳酒中去除S2-
Xuxu Wang1, Jianfeng Ran1, Haisheng Duan2
1Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming, Yunnan 650093, China; State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming, Yunnan 650093, China.
Ultrasonics sonochemistry
|November 18, 2023
概括
超声波增强臭氧有效地从拜耳液中去除硫化物 (S2-),改善生产. 这种方法通过增强质量转移和激素生成,显著提高了硫化物去除效率.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 环境化学环境化学
背景情况:
- 拜耳液中的高硫化物含量会对的消耗,设备腐蚀和生产产生负面影响.
- 有效地去除硫化物对于优化拜耳工艺至关重要.
研究的目的:
- 调查超声波增强臭氧方法的有效性,以从拜耳液中去除硫化物 (S2-).
- 为了最大限度地提高硫化物去除效率,优化反应条件.
主要方法:
- 使用超声波增强臭氧 (US/O3) 系统去除硫化物.
- 多种参数包括反应持续时间,氧气流速,超声波功率和温度.
- 使用电子磁共振 (EPR) 和X射线光电谱 (XPS) 来分析反应机制.
主要成果:
- 在最佳条件下 (20分钟,80 L/h O2,60 W US,60°C) 达到最大硫化物去除效率93.83%.
- 与仅使用臭氧相比,US/O系统的清除效率提高了25.34%.
- 分析证实了自由基含量增加和硫化物完全氧化为硫酸盐 (SO2-).
结论:
- 超声波增强显著改善了从拜耳液体中以臭氧为基础的硫化物去除.
- US/O3方法增强了质量转移和基生成,导致了高效的硫化物氧化.
- 这项技术为减轻硫化物在生产中的不利影响提供了一个有前途的解决方案.
相关概念视频
Oxidative Cleavage of Alkenes: Ozonolysis
10.5K
In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
10.5K
Electrophilic Aromatic Substitution: Sulfonation of Benzene
6.1K
Sulfonation of benzene is a reaction wherein benzene is treated with fuming sulfuric acid at room temperature to produce benzenesulfonic acid. Fuming sulfuric acid is a mixture of sulfur trioxide and concentrated sulfuric acid.
6.1K
Precipitation and Co-precipitation
1.8K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
1.8K
Preparation and Reactions of Sulfides
4.8K
Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
4.8K
Coagulation
307
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
307


