一个热量和质量流合系统的平稳状态热力学
Karol Makuch1, Robert Hołyst1, Konrad Giżyński1
1Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warszawa, Poland.
The Journal of chemical physics
|November 20, 2023
概括
这项研究将热力学原理应用于库埃特流中的理想气体,揭示了内部能量的基本关系. 它引入了一个极端原理,用于识别非平衡系统中的稳定状态.
科学领域:
- 热力学是一种热力学.
- 流体动力学 流体动力学
- 统计力学 统计力学
背景情况:
- 平衡热力学传统上描述了封闭系统中的能量交换.
- 了解非平衡系统对于更广泛的热力学应用至关重要.
- 库埃特流提供了一个明确的系统,用于研究流体动力学和能量转移.
研究的目的:
- 用热力学方法描述Couette流中理想气体的全球能量交换.
- 推导出这个系统的内部能量和状态参数之间的基本关系.
- 分析非平衡过渡,并建立稳定的稳定状态的原则.
主要方法:
- 在Couette流程框架内建模理想气体的行为.
- 对内部能量的基本热力学关系的推导.
- 系统转换的分析和稳定状态的识别,使用极端原理.
主要成果:
- 在理想气体Couette流中建立了一个热力学类型的能量交换描述.
- 导出了将内部能量与状态参数连接起来的基本关系.
- 一个极端原理被假定,成功地确定了稳定的非平衡稳定状态.
结论:
- 这项研究证明了热力学概念对非平衡系统的适用性,例如理想气体库埃特流.
- 导出极点原理提供了一种方法来确定这些系统中稳定的稳定状态.
- 开发的稳态热力学框架与平衡热力学有很大的相似之处.
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